energyNP.com  
Tel
98419-70122 
Email
energyNP@hotmail.com
  98510-17799     
Viber 98510-91900 Skype Ghimire56
Menu

 
 
News  
Back to energy news list >>>
 

 
 
 Air Conditioner
 Battery
 Booster Pump
 Charger
 Cold Storage Room
 Electric Power Tools
 Electric Water Heater
 Garbage Disposal
 Station
 Generator
 Heat Pump
 Inverter
 Power Supply
 Rectifiers
 Self Priming Pump
 Solar Energy
 Solar Water Heater
 Transformer
 UPS
 Voltage Stabilizer
 Wind Energy
 
  Magnesium Conductor Developed for Energy Storage

Movement towards a more energy-efficient society means that the need for high-capacity, cost-effective batteries is greater than ever. Magnesium is a promising material for such solid-state batteries owing to its abundance, but its practical application is limited by the poor conductivity of magnesium ions (Mg2+) in solids at room temperature. Recently, researchers from Japan have developed an Mg2+ conductor with a practically applicable superconductivity of 10-3 S cm-1, overcoming this decades-long roadblock.

Masaaki Sadakiyo, Tokyo University of Science

The development of highly efficient energy storage devices that can store renewable energy is crucial to a sustainable future. In today’s world, solid-state rechargeable lithium ion (Li+) batteries are the state of the art. But lithium is a rare earth metal, and society’s dependence on the element is likely to lead to a rapid decline in resources and subsequent price hikes.

Magnesium ion (Mg2+)-based batteries have gained momentum as an alternative to Li+. The earth’s crust holds ample magnesium, and Mg2+-based energy devices are said to have high energy densities, high safety, and low cost. But the wide application of Mg2+ is limited by its poor conductivity in solids at room temperature. Mg2+ has poor solid-state conductivity because divalent positive ions (2+) experience strong interactions with their neighbouring negative ions in a solid crystal, impeding their migration through the material.

This hurdle was recently overcome by a research team from the Tokyo University of Science (TUS). In their new study published online on 4 May 2022 and on 18 May 2022 in volume 144 issue 19 of the Journal of the American Chemical Society, they report for the first time, a solid-state Mg2+ conductor with superionic conductivity of 10?3 S cm?1 (the threshold for practical application in solid-state batteries). This magnitude of conductivity for Mg2+ conductors is the highest reported to date. According to Junior Associate Professor Masaaki Sadakiyo of TUS, who led the study, “In this work, we exploited a class of materials called metal–organic frameworks (MOFs). MOFs have highly porous crystal structures, which provide the space for efficient migration of the included ions. Here, we additionally introduced a ‘guest molecule,’ acetonitrile, into the pores of the MOF, which succeeded in strongly accelerating the conductivity of Mg2+.” The research group further included Mr Yuto Yoshida, also from TUS, Professor Teppei Yamada from The University of Tokyo, and Assistant Professor Takashi Toyao and Professor Ken-ichi Shimizu from Hokkaido University.

The team used a MOF known as MIL-101 as the main framework and then encapsulated Mg2+ ions in its nanopores. In the resultant MOF-based electrolyte, Mg2+ was loosely packed, thereby allowing the migration of divalent Mg2+ ions. To further enhance ion conductivity, the research team exposed the electrolyte to acetonitrile vapours, which were adsorbed by the MOF as guest molecules.

The team then subjected the prepared samples to an alternating current (AC) impedance test to measure ionic conductivity. They found that the Mg2+ electrolyte exhibited a superionic conductivity of 1.9×10?3 S cm?1. This is the highest ever reported conductivity for a crystalline solid containing Mg2+.

To understand the mechanism behind this high conductivity, the researchers carried out infrared spectroscopic and adsorption isotherm measurements on the electrolyte. The tests revealed that the acetonitrile molecules adsorbed in the framework allowed for the efficient migration of the Mg2+ ions through the body of the solid electrolyte.

These findings of this study not only reveal the novel MOF-based Mg2+ conductor as a suitable material for battery applications, but also provide critical insights into the development of future solid-state batteries. "For a long time, people have believed that divalent or higher valency ions cannot be efficiently transferred through a solid. In this study, we have demonstrated that if the crystal structure and surrounding environment are well-designed, then a solid-state high-conductivity conductor is well within research,” explains Dr Sadakiyo.

When asked about the research group’s future plans, he reveals, “We hope to further contribute to society by developing a divalent conductor with even higher ionic conductivity.”

[9 August, 2022 / world-energy.org ]   
 
 
UPS Nepal Kathmandu
 
Voltage Stabilizer Nepal Kathmandu
 
Solar Water Heater Nepal Kathmandu
 
Solar Water Heater Nepal Kathmandu
 
GREE Air Conditioner Residential Nepal Kathmandu
 
Gree Air Dehumidifier Nepal Kathmandu
Gree Dehumidifier
 
Gree Air Purifier Kills Novel Coronavirus Nepal Kathmandu
 
Battery Charger Nepal Kathmandu
 
Electric Water Heater Nepal Kathmandu
 
Complete Power Solution
 
 
 
 
Solar Water Heater Nepal Kathmandu Solar Energy Nepal Kathmandu Wind Power Nepal Kathmandu Power Generator Nepal Kathmandu Voltage Stabilizer Nepal Kathmandu Transformer Nepal Kathmandu AirConditioner Nepal Kathmandu Battery Nepal Kathmandu UPS System Nepal Kathmandu Rectifier Nepal Kathmandu
 
 
Link: The Official Portal of Goverment of Nepal Nepal Electricity Authority Nepal Alternative Energy Promotion Centre Nepal Telecom Nepal Department of Agriculture Nepal Department of Industry wow Nepal! Nepal Global Buying SIMONES Industries|Nepal Power Solution
  Nepal Goverment Nepal Electricity Authority Nepal Alternative Energy Promotion Centre Nepal Telecom Nepal Department of Agriculture Nepal Department of Industry wow-Nepal | Nepal Global Buying SIMONES Industries |Nepal Power Solution
 
Fair: Investment Summit Nepal Himalayan Hydro Expo Nepal Kathmandu China International Import Expo China Import and Export Fair China-South Asia Exposition Guangzhou Int’l Refrigeration, Air-Condition, Ventilation, Air-Improving Equipment Exhibition Guangzhou International Solar Photovoltaic Exhibition Asia Battery Sourcing Fair
  Investment Summit Nepal Himalayan Hydro Expo Nepal China International Import Expo China Import and Export Fair China-South Asia Exposition Int'l Refrigeration, Air-Condition Fair Int'l Solar Photovoltaic Exhibition Asia Battery Sourcing Fair
 
Copyright @ 2014 All right reserved. Simones Industries